Charge transfer device

ABSTRACT

An information storage and transfer device which has a plurality of capacitors and switching MOS-FET&#39;&#39;s between said capacitors, in which there are a plurality of island areas which serve as source and drain regions of the MOS-FET and which island areas are separated by a plurality of gutters.

United States Patent [191 Ando et a1.

[ Nov. 19, 1974 1 CHARGE TRANSFER DEVlCE [75] Inventors: Tetsuo Ando, Ebina-machi; Yoshimi Hirata, Hatano, both of Japan [73] Assignee: Sony Corporation, Tokyo, Japan [22] Filed: Dec. 5, 1972 [21] Appl. N0.: 312,332

[30] Foreign Application Priority Data Dec. 11, 1971 Japan 46-100410 [52] US. Cl 29/578, 29/580, 29/591, 357/24 [51] int. Cl. H011 11/00, H011 15/00 [58] Field of Search 317/235 B, 235 G, 235 AK, 317/235 HJ; 307/221 D, 304; 29/579-591; 148/175 [56] References Cited OTHER PUBLICATIONS Electronics, The New Concept for Memory and lmagine: Charge Coupling by Altman, pages 50-59, June 21,1971.

IBM Tech Discl Bul., Fabrication of Monolithic lntegrated Circuit Structure 110-111, June 1966. Phillips Res Repts., Local Oxidation of Silicon by Appels et a1., pages 118-132, April 1970.

IBM Tech Discl Bul., MOSFET Structures Using Selective Epitaxial Growth by Terman, pages 3279-80, April 1971.

by Ames et al., pages Primary Examiner-Andrew J. James Attorney, Agent, or Firml-1ill, Gross, Simpson, Van Santen, Steadman, Chiara & Simpson [57] ABSTRACT An information storage and transfer device which has a plurality of capacitors and switching MOS-FETs between said capacitors, in which there are a plurality of island areas which serve as source and drain regions of the MOS-FET and which island areas are separated by a plurality of gutters.

2 Claims, 24 Drawing Figures PATENTELNUV 1 9:914 848,328

snsnznr 3 F .5 (PRIOR ART) CHARGE TRANSFER DEVICE BACKGROUND OF THE INVENTION This invention relates to an information storage and transfer device, and more particularly to a monolithic semiconductor apparatus adapted for storing and sequentially transferring electric charges which represent information. v

Such devices are often called bucket-brigade devices and certain original forms of such devices were first disclosed at the 1970 International Solid State Circuits Conference by F. L. I. Sangster of Philips Research Laboratory. Subsequently, a United States Patent disclosing an original of such device was issued on Nov. 16, 1971 as US. Pat. No. 3,621,283.

The general concept of a bucket-brigade device, hereinafter sometimes referred to as B.B.D.", was also described in an article in the Philips Technical Review, vol. 31, I970, No. 4, pp. 98-110, entitled The bucket-brigade delay line, a shift register for analogue signals".

In this article, the underlying concept of the B.B.D. was described by pointing out that the principle of such a register is quite simple. Sampled values of an analogue signal are stored in the form of charges on a series of capacitors. Between each of these storage capacitors is a type of switch that transfers the charges from one capacitor to the next on a command from a clock pulse. Since each storage capacitor cannot take up its new charge until it has passed on the old one, only half the capacitors carry information and the ones in betweeen are empty.

The B.B.D. is utilized as shift registers, memory devices or image sensors built in one semiconductor chip.

OBJECTS OF THIS INVENTION It is an object of the present invention to provide an improved device for information storage and transfer.

It is another object of the invention to provide an improved bucket-brigade device utilizing an improved form of MOSFET as switching devices. The term MOS-FET" as used herein refers to a metal-oxidesemiconductor field elTect transistor.

It is another object of the invention to provide improved transfer efficiency of the information of such a device.

BRIEF DESCRIPTION OF THE DRAWINGS FIGS. 8 to 24 diagrammatically illustrate process steps by which the structure of the present invention may be fabricated.

DESCRIPTION OF THE PRIOR ART FIG. I shows in a diagrammatic cross-sectional view a known form of B.B.D. It comprises a semiconductor body I of silicon having an N-type conductivity, at plurality of P-type areas, the first group of island areas 2a, 2b, 2c and a second group 3a. 311 at a major face of the silicon substrate 1, arranged uni-directionally. an insulating layer 4, for example silicon-dioxide (SiO covering the plural areas and the major surface of the silicon, a plurality of metal layers, including a first group 5a, 5b and 5c and a second group 6a and 6!). on the insulating layer 4, an input terminal area 7 of P-typc conductivity making a P-N junction with the substrate 1. The first group of metal layers 5a, 5b, and 5c are electrically connected to each other, where the first gate potential 4), is applied simultaneously.

The second group of metal layers 6a and 6b are electrically connected to each other. where the sccond gate potential (b is applied simultaneously.

The first metal-oxide-semiconductor field effect transistor (MOS-FET) Trl consists of one of the first island group 2a (source region), one of the second island group 3a (drain region), a silicon-dioxide layer 4 and I one of the second metal group 6a (gate electrode).

The second MOS-FET Tr.2 similarly consists of the islands 3a (source region), 2b (drain region), isolating layer 4 and the metal layer 5b (gate electrode).

The third and fourth transistors also similarly consist of corresponding elements, as shown in FIG. I.

These plural transistors operate as switches, as described in the aforesaid article in the Philips Technical Review.

Capacitors consist of metal-insulating layer semiconductor island components, such as C 1, C2 and C3. The term metal-insulating layer semiconductor will herein be referred to as MIS.

FIG. 1 is a diagrammatical cross-sectional view of one form of prior art B.B.D.;

FIG. 2 is a circuit with which the device of FIG. 1 may be employed;

FIG. 3 diagrammtically illustrates the functioning of the device with respect to time;

FIG. 4 is a chart to explain a phenomenon which occurs in the prior art device of FIG. 1;

FIG. 5 is an enlarged fragmentary view of a portion of the prior art B.B.D. shown in FIG. 1;

FIG. 6 is a diagrammatic cross-sectional view of a charge transfer device embodying the present invention;

FIG. 7 is an enlarged fragmentary view of a portion of FIG. 6 showing this invention; and

FIG. 2 shows the equivalent circuit of the B.B.D. of FIG. 1 including capacitors C1, C2, and C3 and MOS FETs Tr2, Tr3, Tr3.

In FIG. 3, potential diagrams are shown in full lines. Potentials d), and applied to gate lines are select between 0 volt and negative V volt sequentially in order to transfer charges, such as minority carriers which rep resent information.

When the potential is of higher voltage, such as, 0 (zero) volts, the MOS-FET switches are closed and the capacitors store the information. When the potential is of lower voltage such as Vd) volt, the switches are opened and the capacitors are discharged.

In the periods t1, t3, t5 and t7, the higher voltage (i.e., zero), is applied on both potentials d)! and 2, and the information is stored in each capacitor.

In periods t2 and t6, the lower pulse Vd) volt is applied on only the potential (12.

On the other hand at the period t4, V4: volt is applied on only the potential 1.

The information is transferred in these periods t2, t4 and [6 from a certain capacitor to the next.

The maximum electric charge which is stored and transferred is Q=( VVte) C, where V is the negative gate voltage shown in FIG. 3, Vte is the effected threshold voltage of the MOS-FET Trl etc. and C is the capacitance of the capacitor C1 etc. in FIGS. 1 and 2.

However, the transfer or transport efficiency is not enough for high speed clock pulses such as MHZ or greater which are used in video signal systems.

The changing value of voltage of island areas is shown in the chart of FIG. 4 corresponding to each of the periods t1, t2 and so forth.

The information has a lot of states between the maximum value Qmax (VVte)C and the minimum value Qmin 0. When the charges Qmax [l] and Qmin [O] are transferred from the island area 2b to 3b, the source and drain regions of Tr3, we observed that the information [0] is changed during transfer period.

First of all in period t1, the capacitor C1 is filled with information charges and the area 2b is held at Vl==0 volt, the capacitor C2 is vacant and the area 3b is held at V2 VVte O.

In transfer period :2, (1)2 V O, the channel occurs between the source 2b and the drain 3b, and charges are transferred through this channel. As a result, the area 2b becomes vacant and Vl V Vte, the area 3b becomes filled and V2 vrb.

In the period :3, 62 0, Vl V4) Vte and V2 0, where charges are stored in the capacitor C2.

In the period t4, qbl V, the information [1] changes from the capacitor C2 to the next capacitor C3 and the next information [0] appears in the capacitor CI simultaneously.

In the period t5, Vl W) Vte is holding the information [0] in the capacitor C1 and the capacitor C2 is vacant.

In the next period t6, the information [0] is transferred from C1 to C2. In this period, the modulation of the effective threshold voltage Vte is obtained and VI becomes V Vte AVte) and V2 becomes 2V (Vte A Vte).

In the period [7, VI becomes Vtb- Vte AVte) and V2 becomes Vrb Vte A Vte). Ideally, V1 should be V vte and V2 should be also Vd) Vte.

It is believed that the cause of the reduction of the efficiency lies in the fact that the potential of the drain region has an effect on the value Vte and the maximum value of the transferred information.

The structure of the device is considered to cause these effects on the value Vte at the channel region of the MOS-FET, especially due to the position of the drain region of each MOS-FET.

The effect of a drain modulation is explained in FIG. 5, where an enlarged partial view of the B.B.D. of FIG. 1. Only one MOS-FET is shown there, and this comprises a semiconductor substrate I of N-type, one of the first group of island areas 2 of P-type semiconductor material, one of the second group of island area 3 of P-type semiconductor material, an insulating layer 4 (SiO a gate metal electrode 5, a P-N junction jS and jD, a depletion layer 8 caused by the back-biased P-N junctions, a channel region 9 between island areas, a line of electric force are shown at 10.

When the line of electric force 10 extends to the edge 11 of the junction jS, it changes the value Vte.

To enlarge the distance between two neighboring junctions jS and fl), that is, the channel length, results I However, a long channel reduces the current amplification factor of the MOS-FET and causes also the reduction of the transfer velocity of the information.

DESCRIPTION OF THE PREFERRED EMBODIMENT FIG. 6 shows the improved B.B.D. of this invention. As shown, there is provided a semiconductor body 31, such as N-type silicon substrate: a plurality of gutters 30 in the body 31; a plurality of the island areas 320. 33a, 32b and 33b of P-type silicon arranged unidirectionally on the N-type substrate; an insulating layer 35 such as silicon-dioxide (SiO on the uneven surface of the silicon making channel region 35 between the P- type area islands; a plurality of metal layers 36a. 37a, 36 b and 37b disposed on the SiO; layer 34 the first group of metal electrodes 36a and 36b being connected to each other by a lead extending to the first end termi nal T1; the second group of metal electrodes 37a and 37b being connected by another lead extending to the second end terminal T2; an input area 38 of P-type silicon; and an input electrode 39 connected to the third terminal T3.

A plurality of MOS-FETs TrI, Tr2 and Tr3 are formed and arrayed uni-directionally.

The first transistor Trl consists of P-type island'32a forming a source region, a next island 33a forming a drain region, an insulating layer 34 forming a gate insulator and a metal layer 37a forming a gate electrode. Other transistors are similarly formed.

The equivalent circuit of the B.B.D. is also represented in FIG. 2. This is also operated in accordance with the diagram shown in FIG. 3. Selected potentials 4:1 and (12 are applied on terminals TI and T2 respectively.

FIG. 7vshows an enlarged partial view of the B.B.D. of the present invention and comprises an N-type silicon substrate 20; two neighboring island areas 22 and 23 of P-type an insulating layer 24 (SiO which covers the uneven surface of the silicon; a metal gate electrode 25 which forms the channel region 26 beneath the SiO layer 24; and a depletion layer 27 which is formed when P-N junctions 1S and jD are back-biased by transferring charge and gate potential. In this structure the array of P-type island areas 22 and 23 are deposited higher than the channel region 26, forming the gutter 21 between two island areas 22 and 23. The shape of the P-N junction J8, 1D is flat and there is no curvature in the cross-sectional direction along the array of MOS-FETs.

The line of electric force 28 is shown in the figure. and has a negligible small influence on thechannel re gion and the value Vte, because the line 28 merely extends to the edge portion 29 of the source area 22 from the drain area 23.

As a result of this structure, the small amount A Vte in FIG. 4 becomes approximately zero, and the constant value of Vte makes the transfer efficiency of the charge larger than the prior art without reduction of the transport velocity.

METHOD OF FABRICATING THE STRUCTURE OF THE PRESENT INVENTION A first method of fabrication is shown in FIG. 8 to FIG. 13 and will now be described. In the N-type silicon 40 (FIG. 8), a P-type layer 41 is formed by a diffusion technique (FIG. 9). A thermal silicon-dioxide (SiO layer 42 is formed on the P-type layer and etched selectively to expose the silicon surface (FIG. The P- type layer 41 is selectively etched chemically so that the N-type substrate is exposed (FIG. 11) and a plurality of islands are formed arrayed unidirectionally. A second insulating layer 44 is formed by oxidation covering the exposed N-type surface and P-type islands (FIG. 12). A metal layer, for example aluminum (Al), is deposited on the second insulating layer 44 and selectively etched forming a plurality of gate electrodes 45 (FIG. 13). I

A second method of fabrication of a device embodying the present invention is shown in FIG. 14 to FIG. 19. The N-type silicon substrate 40 is covered by a Si N layer 46 (FIG. 14) and the layer 46 is etched selectively making a plurality of windows (FIG. 15). After selective thermal-oxidation a thick silicondioxide (SiO layer 47 (FIG. 16) is formed, and the silicon-nitride layer (Si N is removed (FIG. 17). The P-type layer is selectively formed by a diffusion technique forming a plurality of island areas unidirectionally arrayed (FIG. 18). The depth of the layer 41 is shallower than the bottom of the SiO layer 47. After the SiO layer 47 is removed, the second oxide layer 44 is formed covering the N-type surface and P-type island areas. The plurality of metal layers 45 deposited (FIG. 19) to form gate electrodes.

A third method of fabrication is shown in FIG. 20 to FIG. 24. A gate insulator 44, such as SiO is formed on the N-type silicon substrate 40 (FIG. 20), and etched selectively (FIG. 21). Double epitaxial layers 48 and 49 are formed on the exposed silicon surface. The first layer 48 is N-type, the same as the substrate 40, and the second layer 49 is of P-type forming a plurality of island areas unidirectionally. The final insulating layer 50 is deposited on the island layer and the gate oxide layer (FIG. 23). A plurality of gate metal layers 45 are detively forming a P-type layer by diffusion technique to form a plurality of island areas unidirectionally arrayed, the depth of the P-type layer being shallower than the bottom of the silicon dioxide layer; removing said first silicon dioxide layer; forming a second oxide layer covering the N-type surface of said substrate and the P-type island areas; and depositing a plurality of metal layers to form gate electrodes and each gate electrode covering a portion of the N-type substrate and overlying a substantial portion of an adjacent P-type layer.

2. The method of forming a charge transfer device which includes: taking an N-type silicon substrate; forming a gate oxide insulator on said substrate; selectively removing said gate insulator to form a plurality of islands, forming double epitaxial layers on the islands of the substrate surface, the first layer being of N-type and the second layer being of P-type, said plurality of island areas located in a line; depositing a final insulating layer on said island layer and said gate oxide layer; and forming a plurality of gate metal layers on the surface of said final insulating layer and each gate metal layers covering an island and overlying a substantial portion of an adjacent P-type layer. 

1. THE METHOD OF FORMING A CHARGE TRANSFER DEVICE WHICH INCLUDES: TAKING AN N-TYPE SILICON SUBSTATE; COVERING SAID SUBSTRATE WITH A SILICON NITRIDE LAYER; SELECTIVELY ETCHING AWAY PORTIONS OF SAID SILICON NITRIDE LAYER AND SAID SUBSTRATE TO FORM A PLURALITY OF WINDOWS HAVING BOTTOMS BELOW THE SILICON NITRIDE LAYER, FORMING A FIRST LAYER OF THICK SILICON DIOXIDE BY THERMAL OXIDATION IN SAID WINDOWS, REMOVING THE SILICON NITRIDE LAYER; SELECTIVELY FORMING A P-TYPE LAYER BY DIFFUSION TECHNIQUE TO FORM A PLURALITY OF ISLAND AREAS UNIDIRECTIONALLY ARRAYED, THE
 2. The method of forming a charge transfer device which includes: taking an N-type silicon substrate; forming a gate oxide insulator on said substrate; selectively removing said gate insulator to form a plurality of islands, forming double epitaxial layers on the islands of the substrate surface, the first layer being of N-type and the second layer being of P-type, said plurality of island areas located in a line; depositing a final insulating layer on said island layer and said gate oxide layer; and forming a plurality of gate metal layers on the surface of said final insulating layer and each gate metal layers covering an island and overlying a substantial portion of an adjacent P-type layer. 